Stuart Anderson came with an idea of embedding K3,3 into a Möbius band whose nonorientability highlights non-planarity of the graph:
I was just looking at the bipartite graph page, and I noticed a different way to see that K3,3 is nonplanar. (No doubt there are many ways to see this.) If the edges AE and WC are connected with straight lines instead of the curves in the figure, you can visualize the graph as a Möbius strip in 3d. Rectangle WABG is a section of the strip, BGEC is the next section along the strip, and ECWA is a third section connecting the first two and completing the strip. Where edges WC and AE cross, we are seeing the half twist in the section ECWA, looking at the strip edge on. Once you see the graph this way, it is obvious how to draw it on a Möbius strip. Just draw three lines across the width of the strip and a line around the edge. The points of intersection are the vertices of K3,3 and the line segments connecting them are the edges. But if K3,3 were planar, it would have a natural orientation inherited from the plane, hence could not be filled with a nonorientable surface. (If K3,3 were imbedded in the plane, the path around the Möbius strip would now appear to follow a patchwork of orientable areas, and so would not reverse orientation.) Therefore K3,3 is nonplanar.
I think this is interesting, because the other two dimensional embedding mentioned (in a torus) can't be used so directly to prove K3,3 is nonplanar, because the torus is orientable. Perhaps other topological properties of the torus could be used instead, but none is as obviously incompatible with a plane embedding as nonorientability.
The same trick works for K5 as well: Taking the vertices 4 at a time you can see trapezoidal strips that you can think of as segments of a Möbius strip. Follow each strip to the edge and imagine that the paper folds under and connects to the next trapezoid. After going around 5 times, you have of course a Möbius strip because you've made an odd number of folds. To draw this graph on a Möbius strip, place 5 equally spaced points along its edge and connect them across the strip with a zigzag line. This way of folding a Möbius strip is very closely related to the cut-the-knot logo, omitting the extra knots at the corners.
Isn't it interesting that the cut-the-knot logo can be used to prove K5 is nonplanar?